HIGH-RESOLUTION ELECTRONIC SPECTROSCOPY OF JET-COOLED HEXAFLUOROBENZENE AND 1,3,5-TRIFLUOROBENZENE CATIONS, C6F6+ AND C6F3H3+

被引：20

作者：

YU, L

FOSTER, SC

WILLIAMSON, JM

MILLER, TA

机构：

[1] Laser Spectroscopy Facility, Ohio State University, Department of Chemistry, Columbus

[2] Department of Chemistry, Florida State University, Tallahassee

来源：

JOURNAL OF CHEMICAL PHYSICS | 1990年 / 92卷 / 10期

关键词：

D O I：

10.1063/1.458399

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The nearly completely rotationally resolved electronic spectra of two aromatic organic ions have been obtained. Rotationally cold ions, C6 F6+ and C6 F3 H3 +, are produced by laser ionization in a supersonic free jet expansion and probed via laser induced fluorescence with a very high resolution pulse-amplified cw ring dye laser. The spectra are analyzed to obtain band origins, rotational constants, Coriolis and Jahn-Teller parameters. © 1990 American Institute of Physics.

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页码：5794 / 5800

页数：7

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