SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL TETRANUCLEAR COMPLEX OF GOLD(I) WITH O-CARBORANE DERIVATIVES AS LIGANDS

被引：39

作者：

CRESPO, O

GIMENO, MC

JONES, PG

LAGUNA, A

机构：

[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN,E-50009 ZARAGOZA,SPAIN

[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 22期

关键词：

D O I：

10.1039/c39930001696

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of the dinuclear complex [(AuCl)2(B10H10C2(PPh2)2}] in dichloromethane with 1,2-dimercapto-1,2-dicarba-closo-dodecarborane and Na2CO3 results in the formation of the tetranuclear complex [Au4(S2C2B10H10)2{(PPh2)2C2B10H10)2]; the structure was confirmed by X-ray studies and shows an eight-membered Au4S4 ring with a short transannular gold-gold interaction,

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页码：1696 / 1697

页数：2

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