CARBON-CARBON BOND FORMATION IN HELICAL NICKEL(II) COMPLEX, CIS-BIS[2-N-(PHENYLMETHYLIDENEAMINE)BENZENETHIOLATO]NICKEL(II)

被引:20
作者
KAWAMOTO, T [1 ]
KUSHI, Y [1 ]
机构
[1] INST MOLEC SCI, COORDINAT CHEM LABS, OKAZAKI, AICHI 444, JAPAN
关键词
D O I
10.1246/cl.1992.893
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of 2-phenylbenzothiazoline with nickel(II) acetate tetrahydrate leads to cis-bis[2-N-(phenylmethylideneamine)benzenethiolato]nickel(II) (1) and two ligands in 1 are joined through a C-C bond to form a complex having two chiral centers (2). The X-ray structural analysis of 2 establishes the bond patterns of the delocalized ligand.
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页码:893 / 896
页数:4
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