STUDIES ON THE REACTIONS OF SILYL ENOL ETHER WITH PERFLUORO-ORGANIC COMPOUNDS .2. ONE-POT REACTION FOR THE SYNTHESIS OF FLUORINATED BETA-DIKETONES

被引：13

作者：

HUANG, WY

WU, YM

机构：

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1992年 / 59卷 / 02期

关键词：

D O I：

10.1016/S0022-1139(00)82407-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fluorinated beta-diketones have been synthesized in high yield from the one-pot reaction of silyl enol ethers with perfluoroalkyl iodides initiates with Na2S2O4/NaHCO3, followed by treatment with diethylamine and acid hydrolysis.

引用

页码：179 / 183

页数：5

共 23 条

[1] DECARBETHOXYLATION OF PERFLUOROACID ESTERS [J].

BERGMAN, E .

JOURNAL OF ORGANIC CHEMISTRY, 1958, 23 (03) :476-477

[2]

BERGMANN ED, 1961, J CHEM SOC, P3278

[3] A NEW PRACTICAL SYNTHESIS OF SILYL ENOL ETHERS .1. FROM SIMPLE ALDEHYDES AND KETONES [J].

CAZEAU, P ;

DUBOUDIN, F ;

MOULINES, F ;

BABOT, O ;

DUNOGUES, J .

TETRAHEDRON, 1987, 43 (09) :2075-2088

[4] A NEW PRACTICAL SYNTHESIS OF SILYL ENOL ETHERS .2. FROM ALPHA,BETA-UNSATURATED ALDEHYDES AND KETONES [J].

CAZEAU, P ;

DUBOUDIN, F ;

MOULINES, F ;

BABOT, O ;

DUNOGUES, J .

TETRAHEDRON, 1987, 43 (09) :2089-2100

[5]

COCKERILL AF, 1973, CHEM REV, V73, P551

[6] CHEMISTRY OF CARBANIONS .18. PREPARATION OF TRIMETHYLSILYL ENOL ETHERS [J].

HOUSE, HO ;

CZUBA, LJ ;

GALL, M ;

OLMSTEAD, HD .

JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (08) :2324-&

[7]

HUANG WY, 1986, ACTA CHIM SINICA, V44, P642

[8]

HUANG WY, 1989, YOUJI HUAXUE, V9, P38

[9]

HUANG WY, 1985, ACTA CHIM SINICA, V43, P173

[10]

HUANG WY, 1991, CHINESE J CHEM, V9, P528

← 1 2 3 →