REACTIONS OF HNNO+ AND NNOH+ IONS WITH CH4 AND NO AS A FUNCTION OF RELATIVE KINETIC-ENERGY

被引：8

作者：

JAVAHERY, G ^{[1
]}

GLOSIK, J ^{[1
]}

TWIDDY, ND ^{[1
]}

FERGUSON, EE ^{[1
]}

机构：

[1] UNIV PARIS 11,PHYSICOCHIM RAYONNEMENTS LAB,F-91405 ORSAY,FRANCE

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1990年 / 98卷 / 03期

关键词：

D O I：

10.1016/0168-1176(90)80003-L

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Rate constants for the reaction of the two isomers of protonated N2O, HNNO+ and NNOH+, with CH4 and NO have been measured as a function of relative kinetic energy. The CH4 measurements allow a determination of the proton affinity of N2O on N of 131.5 ± 1 kcal mol-1 and an isomeric energy difference of 6.2 ± 0.5 kcal mol-1. This latter value should be compared with the recently obtained theoretical value of 7.1 kcal mol-1. © 1990.

引用

页码：225 / 233

页数：9

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