2-TRIMETHYLSILYLMETHYL ALLYLTRIMETHYLSILANE, PRECURSOR OF CARBOCYCLES AND HETEROCYCLES WITH A METHYLENE GROUP

被引:19
作者
GUYOT, B [1 ]
PORNET, J [1 ]
MIGINIAC, L [1 ]
机构
[1] UNIV POITIERS,SYNTHESE ORGAN LAB,CNRS,UA 574,40 AVE RECTEUR PINEAU,F-86022 POITIERS,FRANCE
关键词
D O I
10.1016/S0040-4020(01)86438-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
2-Trimethylsilylmethyl allyltrimethylsilane, easily prepared from isobutene, allows a convenient one-pot synthesis of functional methylene cycloalcanes from bis-acetals and of 4-methylene N-alkyl piperidines from primary amines and polyoxymethylene.
引用
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页码:3981 / 3988
页数:8
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