PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF [SN(N(SIME3)2)2(MU-O2)]2, A RARE EXAMPLE OF A BIS(1,2-MU-PEROXO)-BRIDGED METAL-COMPLEX

被引：18

作者：

CHORLEY, RW

HITCHCOCK, PB

LAPPERT, MF

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 07期

关键词：

D O I：

10.1039/c39920000525

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystalline binuclear bis(amido)tin(IV) complex [Sn{N(SiMe3)2}2(mu-O2)]2 has been characterised by X-ray diffraction; the molecule possesses a structural feature highly unusual for metal complexes, in which the two tin atoms are doubly-bridged by 1,2-mu-peroxo ligands [<Sn-O> 1.987(7), <O-O> 1.501(10) angstrom; <O-Sn-O> 99.7(3), <Sn-O-O> 100.0(4)-degrees].

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页码：525 / 526

页数：2

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