AN APPROACH TO THE PREPARATION OF CONJUGATED POLYRADICALS

被引：10

作者：

ALEXANDER, C ^{[1
]}

FEAST, WJ ^{[1
]}

机构：

[1] SCI LABS,DEPT CHEM,INTERDISCIPLINARY RES CTR POLYMER SCI,S RD,DURHAM DH1 3LE,ENGLAND

来源：

POLYMER BULLETIN | 1991年 / 26卷 / 03期

关键词：

D O I：

10.1007/BF00587965

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new conjugated polymer, (poly(4-ethynylphenyl)diphenylmethyl) was prepared and characterized. The preparation involved the synthesis of a new acetylenic monomer, (4-ethynylphenyl)diphenylmethanol, which was polymerized by the well-defined catalysts (t-BuO)2Mo( = CH-t-Bu)(NAr) and [Rh(COD)Cl]2. The resulting conjugated polymer was reacted with thionyl chloride and then reduced with silver to yield a material with pendant triphenylmethyl radicals attached to the conjugated polymer chain.

引用

页码：245 / 252

页数：8

共 25 条

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