INFRARED-INDUCED CHARGE-TRANSFER IN SF6.AR3+ - AN ALTERNATIVE ROUTE TO THE IONIZATION-ENERGY OF SF6+

被引：11

作者：

STACE, AJ

JONES, AB

WINKEL, JF

WOODWARD, CA

机构：

[1] School of Molecular Sciences, University of Sussex, Falmer

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 44期

关键词：

D O I：

10.1021/j100146a001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The infrared excitation of the cluster ion SF6.Ar3+ at a photon energy of 950 cm-1 is observed to promote charge transfer leading to the formation of SF5+. Together with recent measurements of the ionization energies of small argon clusters, this result is used to determine a value for the ionization energy of SF6 as 14.40 +/- 0.06 eV. Since it is assumed that SF6 in the ground state of the complex is neutral and close to its equilibrium geometry, the above value probably constitutes a vertical ionization energy.

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页码：11363 / 11365

页数：3

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