LI5PT2H9, A COMPLEX HYDRIDE CONTAINING ISOLATED [PT2H9](5-) IONS

被引：15

作者：

BRONGER, W

BRASSARD, LA

机构：

[1] Institut für Anorganische Chemie, Technische Hochschule Aachen, D-52056

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 08期

关键词：

HYDRIDES; LITHIUM COMPOUNDS; NEUTRON DIFFRACTION; PLATINUM COMPOUNDS;

D O I：

10.1002/anie.199508981

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A description as vertex‐connected square double pyramid fits the coordination polyhedrons of the two platinum centers in the anion 1 of Li5Pt2H9. The ternary hydride can be synthesized from LiH and Pt sponge under a hydrogen pressure of 1250 bar. The lithium counterions are eight‐ and sevenfold coordinated. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：898 / 900

页数：3

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