EVALUATION AND APPLICATION OF ISOKINETIC RELATIONSHIPS - THE THERMAL-DECOMPOSITION OF SOLIDS UNDER NONISOTHERMAL CONDITIONS

被引：20

作者：

VYAZOVKIN, S

LINERT, W

机构：

[1] Institute for Inorganic Chemistry, Technical University of Vienna, Getreidemarkt 9

[2] Institute for Physico-Chemical Problems, Byelorussian University, Minsk

来源：

JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES | 1994年 / 34卷 / 06期

关键词：

D O I：

10.1021/ci00022a008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two approaches (discriminating (1) and isoconversional (2)) to the evaluation of Arrhenius parameters for the thermal decomposition of solids under nonisothermal conditions are investigated and applied to both modeled and experimental data: Approach (1) allows only for the detection of an isokinetic relationship (IKR) but not for unambiguously estimating its parameters and approach (2) makes it possible not only to detect an IKR but also to determine its parameters. These may in turn be used to obtain information about the actual reaction pathway of the thermally induced process. The thermal decomposition of tetranuclear Cu(II) complexes with various ligands is used as an experimental example.

引用

页码：1273 / 1278

页数：6

共 23 条

[1]

Brown M. E., 1980, REACTIONS SOLID STAT, V22

[2] KINETIC PARAMETERS FROM THERMOGRAVIMETRIC DATA [J].