PHOTOINDUCED DEALKYLATION REACTIONS ON INDENYL AND FLUORENYL FUNCTIONALIZED CYCLOPENTADIENYLTRICARBONYLMETHYL COMPLEXES OF MOLYBDENUM AND TUNGSTEN AND THEIR MOLECULAR-STRUCTURES (ETA-5-ETA-1-C5H4CME2C9H6)MO(CO)3, (ETA-5-ETA-1-C5H4CME2C13H8)W(CO)3 AND [ETA-5-C5H4(CH2)3C13H9)W(CO)3]2

被引：7

作者：

ALT, HG ^{[1
]}

HAN, JS ^{[1
]}

ROGERS, RD ^{[1
]}

机构：

[1] NO ILLINOIS UNIV,DEPT CHEM,DE KALB,IL 60115

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 454卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83237-P

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Upon photolysis the indenyl and fluorenyl functionalized cyclopentadienyl complexes (eta5-C5H4CMe2R)M(CO)3Me (R = C9H7 (indenyl), C13H9 (fluorenyl); M = Mo, W) and (eta5-C5H4(CH2)3C13H9)W(CO)3Me are dealkylated to give methane, the monomeric tricarbonyl complexes (eta5:eta1-C5H4CMe2C9H6)M(CO)3 and (eta5:eta1-C5H4CMe2C13H8)W(CO)3, and the dinuclear complex [(eta5-C5H4(CH2)3C13H9)W(CO)3]2 (6). The molecular structures of (eta5:eta1-C5H4CMe2C9H6)Mo(CO)3 and (eta5:eta1-C5H4CMe2C13H8)W(CO)3 indicate that the C9H6 Unit is sigma-bonded to the metal via the five-membered ring and the C13H8 moiety via a six-membered ring. The dimeric complex 6 is held together by a comparatively long W-W bond (3.2257(6) angstrom).

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页码：165 / 172

页数：8

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