FLASH-PHOTOLYSIS STUDY OF 3-METHYLISOXAZOLO[5,4-B]PYRIDINE

被引:7
作者
DONATI, D [1 ]
PONTICELLI, F [1 ]
BICCHI, P [1 ]
MEUCCI, M [1 ]
机构
[1] UNIV SIENA,IST FIS,I-53100 SIENA,ITALY
关键词
D O I
10.1021/j100376a020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photoreactivity of the title compound has been examined in MeOH, PriOH, MeCN, and MeCN/as-dimethylhydrazine solutions. A ketenimine and a spiroazirine intermediate account for the final products as well as for the transients observed in the flash photolysis experiments. It is also found that acid catalysis plays an important role in the reaction of spiroazirine to oxazolopyridine. © 1990 American Chemical Society.
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页码:5271 / 5274
页数:4
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