REACTOR ENGINEERING MODELS OF COMPLEX ELECTROCHEMICAL REACTION SCHEMES .1. POTENTIOSTATIC OPERATION OF PARALLEL AND SERIES REACTIONS IN IDEAL REACTORS

被引：22

作者：

SCOTT, K

机构：

[1] Teesside Polytechnic Inst, Dep of, Chemical Engineering, Middleborough,, Engl, Teesside Polytechnic Inst, Dep of Chemical Engineering, Middleborough, Engl

来源：

ELECTROCHIMICA ACTA | 1985年 / 30卷 / 02期

关键词：

ACIDS - CHEMICAL REACTIONS - Mathematical Models - ELECTROCHEMISTRY - ELECTRODES;

D O I：

10.1016/0013-4686(85)80088-8

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Mathematical models of complex electrochemical reaction schemes are developed in which mass transport of reactant and products at the electrode surface plays an important part in describing overall reaction rates. Parallel and series reactions are treated in two ideal reactor configurations: batch and plug flow. Cell operation is restricted to potentiostatic operation which allows the model solutions to be obtained in analytical form. The model is used to simulate the behavior of a potentially useful organic synthesis; the electroreduction of oxalic acid to glyoxylic acid.

引用

页码：235 / 244

页数：10

共 5 条

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[5]

SCOTT K, 1977, THESIS U NEWCASTLE U

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