REACTION OF [60]FULLERENE WITH TRIETHYLAMINE

被引：6

作者：

POLA, J

DARWISH, AD

JACKSON, RA

KROTO, HW

MEIDINE, MF

ABDULSADA, AK

TAYLOR, R

WALTON, DRM

机构：

[1] School of Chemistry and Molecular Sciences, University of Sussex, Brighton, BN1

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1995年 / 3卷 / 03期

关键词：

D O I：

10.1080/153638X9508543784

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

[60]Fullerene reacts with neat triethylamine via an electron transfer involving an intermediate C60-radical-anion, to give a salt-like product. This decomposes to [60]fullerene upon either heating, or treatment with ultrasound. EI mass fragmentation of the product indicates an intramolecular abstraction of H from C2H5 by the [60]fullerene moiety.

引用

收藏

页码：299 / 303

页数：5

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