X-RAY PHOTOELECTRON-SPECTROSCOPY INSIGHT INTO THE COORDINATION MODES OF CYANATE IN COPPER(II) COMPLEXES

被引：5

作者：

DAGNANO, A

GARGANO, M

MALITESTA, C

RAVASIO, N

SABBATINI, L

机构：

[1] Dipartimento di Chimica, Universita' degli Studi, 70126 Bari

[2] Centro CNR Metodologie Innovative di Sintesi Organiche, Dipartimento di Chimica, Universita' degli Studi, 70126 Bari

[3] Dipartimento di Chimica, Universita' degli Studi, 70126 Bari

[4] Centro CNR Metodologie Innorative di Sintesi Organiche, Dipartimento di Chimica, Universita' degli Studi, 70126 Bari

[5] Dipartimento di Chimica, Universita' degli Studi, 70126 Bari

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1991年 / 53卷 / 04期

关键词：

D O I：

10.1016/0368-2048(91)85040-Z

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Some copper (II) cyanato complexes have been synthesised and characterised by elemental analysis, IR spectroscopy and X-ray photoelectron spectroscopy. Modified Auger parameters (alpha') have been evaluated and correlated with crystallographic and/or IR information on the coordination mode of cyanate to copper (II). The following trend has been found for alpha' values: high values (higher than 1850 eV) for bridging coordination mode and low values (lower than 1844 eV) for non-bridging structures. Final-state relaxation effects, related to a strong interaction between copper centres in bridging structures, are invoked to explain the trend of alpha' values in the various complexes.

引用

页码：213 / 224

页数：12

共 27 条

[1] LINKAGE ISOMERS OF CYANATE GROUP - O-CYANATO AND N-CYANATO-[TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)] [J].