METALATIONS OF 1-AMINONAPHTHALENE WITH ALME3 AND WITH ZNET2 - SYNTHESES AND CRYSTAL-STRUCTURES OF CYCLOBUTANE-LIKE [ME2AL(N(H)NAPHTHYL)]2 AND CYCLOHEXANE-LIKE [ET2N(N(H)NAPHTHYL).THF]3

被引：41

作者：

DAVIDSON, MG ^{[1
]}

ELILIO, D ^{[1
]}

LESS, SL ^{[1
]}

MARTIN, A ^{[1
]}

RAITHBY, PR ^{[1
]}

SNAITH, R ^{[1
]}

WRIGHT, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1021/om00025a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metalation of 1-aminonaphthalene with AlMe2 produces the planar Al2N2 ring dimer [Me2AI(N(H)naphthyl)]2 (1), in which there is a trans orientation of the N-H protons. Similar metalation of the same primary amine with ZnEt2 produces the chair-shaped Zn3N3 ring trimer [EtZn(N(H)naphthyl).THF]3 (2), in which the ring N-H protons are all cis. Complex 2 is the first trimeric amido Zn complex to be structurally characterized.

引用

页码：1 / 3

页数：3

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