ONE-DIMENSIONAL AROMATIC CRYSTALS IN SOLUTION .6. SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF POLY(BETA-9-ANTHRYLMETHYL L-ASPARTATE)

被引：10

作者：

SISIDO, M ^{[1
]}

OKAMOTO, A ^{[1
]}

EGUSA, S ^{[1
]}

IMANISHI, Y ^{[1
]}

机构：

[1] KYOTO UNIV,DEPT POLYMER CHEM,KYOTO 606,JAPAN

来源：

POLYMER JOURNAL | 1985年 / 17卷 / 12期

关键词：

AROMATIC POLYMERS - Electronic Properties - SOLUTIONS - Spectroscopic Analysis - SPECTROSCOPY - Applications;

D O I：

10.1295/polymj.17.1253

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An aromatic poly( alpha -amino acid) carrying anthryl chromophores, poly(9-anthrylmethyl L-aspartate), was synthesized in a form of a block copolymer with poly( gamma -benzyl DL-glutamate) which functions as a solubilizing component. Electronic interactions in the ground and excited states of this aromatic polypeptide were studied by absorption, fluorescence, circular dichroism, circularly polarized fluorescence, and fluorescence-detected circular dichroism spectroscopy. On the basis of these observations, a scheme was proposed for the electronic states of the anthryl polypeptide.

引用

页码：1253 / 1261

页数：9

共 16 条

[1] A HELICAL POLY(AMINO ACID) HAVING CARBAZOLE SIDE-CHAINS - A CANDIDATE FOR A PHOTOELECTRIC LIQUID-CRYSTAL .2. STEADY-STATE AND TIME-RESOLVED STUDIES OF EXCIMER EMISSION
BIDDLE, D
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[J]. MACROMOLECULES, 1984, 17 (09) : 1751 - 1756
[2] A HELICAL POLY(AMINO ACID) HAVING CARBAZOLE SIDE-CHAINS - A CANDIDATE FOR A PHOTOELECTRIC LIQUID-CRYSTAL .1. SYNTHESIS AND CHARACTERIZATION
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[3] ONE-DIMENSIONAL AROMATIC CRYSTALS IN SOLUTION .4. GROUND-STATE AND EXCITED-STATE INTERACTIONS OF POLY(L-1-PYRENYLALANINE) STUDIED BY CHIROPTICAL SPECTROSCOPY INCLUDING CIRCULARLY POLARIZED FLUORESCENCE AND FLUORESCENCE-DETECTED CIRCULAR-DICHROISM
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[J]. MACROMOLECULES, 1985, 18 (05) : 882 - 889
[4] ONE-DIMENSIONAL AROMATIC CRYSTALS IN SOLUTION .3. SYNTHESIS AND SPECTROSCOPIC PROPERTIES OF POLY(L-1-PYRENYLALANINE)
EGUSA, S
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[J]. CHEMISTRY LETTERS, 1983, (08) : 1307 - 1310
[5] PIEZOELECTRIC PROPERTIES OF BIOLOGICAL POLYMERS
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[J]. QUARTERLY REVIEWS OF BIOPHYSICS, 1983, 16 (01) : 59 - 87
[6] FLUORESCENCE DETECTED CIRCULAR-DICHROISM OF PROTEINS WITH SINGLE FLUORESCENT TRYPTOPHANS
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (16) : 4936 - 4940
[7] ONE-DIMENSIONAL AROMATIC CRYSTALS IN SOLUTION .5. EMPIRICAL ENERGY AND THEORETICAL CIRCULAR-DICHROISM CALCULATIONS ON HELICAL POLY(L-1-PYRENYLALANINE)
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[J]. MACROMOLECULES, 1985, 18 (05) : 890 - 894
[8] CIRCULARLY POLARIZED FLUORESCENCE OF AROMATIC POLY(ALPHA-AMINO ACIDS)
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[9] ONE-DIMENSIONAL AROMATIC CRYSTALS IN SOLUTION .2. SYNTHESIS, CONFORMATION, AND SPECTROSCOPIC PROPERTIES OF POLY(L-2-NAPHTHYLALANINE)
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (12) : 4077 - 4082
[10] ONE-DIMENSIONAL AROMATIC CRYSTAL IN SOLUTION .1. SYNTHESIS, CONFORMATION, AND SPECTROSCOPIC PROPERTIES OF POLY(L-1-NAPHTHYLALANINE)
SISIDO, M
EGUSA, S
IMANISHI, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (04) : 1041 - 1049

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