NOVEL TRANSFORMATION OF FORMYL GROUPS INTO HYDROXYL-GROUPS UTILIZING DEFORMYLATIVE AUTOXIDATION OF ALDEHYDES

被引：7

作者：

KIGOSHI, H ^{[1
]}

IMAMURA, Y ^{[1
]}

SAWADA, A ^{[1
]}

NIWA, H ^{[1
]}

YAMADA, K ^{[1
]}

机构：

[1] NAGOYA UNIV, FAC SCI, DEPT CHEM, NAGOYA, AICHI 464, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 12期

关键词：

D O I：

10.1246/bcsj.64.3735

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structural requirements that cause deformylative autoxidation of aliphatic aldehydes are investigated. Decarbonylation of acyl radicals proceeds smoothly when the alkyl radicals that are formed can be stabilized by allylic conjugation. Further conjugation of the double bond in the allyl radical with a carbonyl or a cyclopropyl group allows position-selective peroxidation of the alkyl radical.

引用

页码：3735 / 3737

页数：3

共 5 条

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[4]

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