STRUCTURE OF DI-MU-ACETATO-MU-OXO-BIS[BIS(2-PYRIDYLMETHYL)AMINE]DIIRON(III) DIPERCHLORATE 0.9-ACETONE SOLVATE

被引：12

作者：

OBRIEN, RJ ^{[1
]}

RICHARDSON, JF ^{[1
]}

BUCHANAN, RM ^{[1
]}

机构：

[1] UNIV LOUISVILLE,DEPT CHEM,LOUISVILLE,KY 40292

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270191005759

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[C28H32Fe2N6O5](ClO4)2.0.9(C3H6O), M(r) = 889.66, triclinic, P1BAR, a = 13.601 (3), b = 13.966 (3), c = 12.341 (3) angstrom, alpha = 100.10 (2), beta = 99.56 (2), gamma = 115.19 (2)-degrees, V = 2010.6 angstrom 3, Z = 2, D(x) = 1.46 g cm-3, Mo K-alpha, lambda = 0.7093 angstrom, mu = 9.12 cm-1, F(000) = 915.2, T = 296 K, final R = 0.057 for 5092 unique reflections. The structure consists of a binuclear cation with two disordered perchlorate counterions and a partial acetone solvate molecule. The Fe-Fe separation is 3.041 (1) angstrom with both Fe atoms octahedrally coordinated by a bridging oxo, two bridging acetate groups, and the facial capping ligand bis(2-pyridylmethyl)amine (bpma). The average Fe-O(oxo) bond distance is 1.792 (3) angstrom and the Fe-O-Fe bond angle is 116.2 (2)-degrees. The pyridine pendants of bpma are located cis to the oxo group.

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页码：2307 / 2310

页数：4

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