([2-(DIMETHYLAMINO)ETHYL]CYCLOPENTADIENYL)TRICHLOROTITANIUM - A NEW-TYPE OF OLEFIN POLYMERIZATION CATALYST

被引：127

作者：

FLORES, JC ^{[1
]}

CHIEN, JCW ^{[1
]}

RAUSCH, MD ^{[1
]}

机构：

[1] UNIV MASSACHUSETTS, DEPT POLYMER SCI & ENGN, DEPT CHEM, AMHERST, MA 01003 USA

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 11期

关键词：

D O I：

10.1021/om00023a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(C(5)H(4)CH(2)CH(2)NMe(2))TiCl3 (1) has been prepared in 96% yield as a highly moisture-sensitive solid which is readily hydrolyzed to a mu-oxo derivative (4). The H-1 NMR spectrum of 1 is consistent with intramolecular coordination of the dimethylamino group to titanium. Compound 1 exhibits relatively low activity as a styrene polymerization catalyst but is remarkably active for both ethylene and propylene polymerizations.

引用

页码：4140 / 4142

页数：3

共 50 条

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