ELECTROLYTIC TRANSFORMATION OF FLUOROORGANIC COMPOUNDS .6. CATIONIC POLAR CYCLOADDITION WITH ANODICALLY PREPARED ALPHA-TRIFLUOROMETHYLATED AND ALPHA-DIFLUOROMETHYLATED N,O-ACETALS - PREPARATION OF FLUOROMETHYLATED TETRAHYDROQUINOLINE AND DIHYDROQUINOLINE DERIVATIVES

被引：22

作者：

FUCHIGAMI, T

ICHIKAWA, S

KANDEEL, ZE

KONNO, A

NONAKA, T

机构：

[1] Department of Electronic Chemistry, Graduate School at Nagatsuta, Tokyo Institute of Technology Nagatsuta, Midori-ku, Yokohama

来源：

HETEROCYCLES | 1990年 / 31卷 / 03期

关键词：

D O I：

10.3987/COM-89-5295

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Anodically prepared α-tri- and α-difluoromethylated N, O-acetals readily underwent [4+ + 2] type polar cycloadditions with styrenes and phenylacetylene in the presence of a Lewis acid to provide the corresponding fluoromethylated tetra- and dihydroquinoline derivatives. © 1990.

引用

页码：415 / 417

页数：3

共 7 条

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[2] FILLER R, 1983, BIOMEDICAL ASPECTS F
[3] ELECTROCHEMICAL GENERATION OF REACTIVE NITROGEN SPECIES .11. ELECTROLYTIC TRANSFORMATION OF FLUOROORGANIC COMPOUNDS .3. HIGHLY REGIOSELECTIVE ANODIC METHOXYLATION OF N-(2,2,2-TRIFLUOROETHYL)AMINES
FUCHIGAMI, T
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (24) : 5489 - 5491
[4] KONNO A, IN PRESS J ORG CHEM
[5] FREE-RADICAL APPROACH TO C-C BOND FORMATION ON A TRIFLUOROMETHYL-SUBSTITUTED CARBON - INTRAMOLECULAR CYCLIZATION
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UEJIMA, M
KOBAYASHI, Y
[J]. CHEMISTRY LETTERS, 1989, (04) : 623 - 624
[6] SYNTHESIS OF TRIFLUOROMETHYL AZOLES USING BUILDING-BLOCKS
TANAKA, K
MITSUHASHI, K
[J]. JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1987, 45 (03) : 269 - 283
[7] 1,1-DIHYDROPERFLUOROALKYLATIONS OF NUCLEOPHILES WITH (1,1-DI-HYDROPERFLUOROALKYL)PHENYLIODONIUM TRIFLATES
UMEMOTO, T
GOTOH, Y
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1986, 31 (02) : 231 - 236

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