CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .211. PENTAISOPROPYLTETRACYCLOUNDECAPHOSPHANE, P11IPR5 - PREPARATION AND STRUCTURE DETERMINATION BY NUCLEAR-MAGNETIC-RESONANCE

被引：8

作者：

BAUDLER, M

JACHOW, H

FLORUSS, A

HASENBACH, J

机构：

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 05期

关键词：

TETRACYCLO[6.2.1.0(2,6).0(5,10)]UNDECAPHOSPHANE, 3,4,7,9,11-PENTAORGANYL; UNDECAPHOSPHA-2,8-ETHANONORADAMANTANE; UNDECAPHOSPHANE(5); PHOSPHANES; POLYCYCLIC;

D O I：

10.1002/cber.19911240527

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pentaisopropyltetracycloundecaphosphane (1) has been obtained by reaction of iPrPCl2 with P4 and magnesium and subsequent thermolysis of the crude reaction product, and has been isolated in 91% purity. According to NMR-spectroscopic investigations, 1 has a constitution analogous to that of the hydrocarbon 2,8-ethanonoradamantane, thus being 3,4,7,9,11-pentaisopropyltetracyclo[6.2.1.0(2,6).0(5,10)]undecaphosphane. Compound 1 is formed as a mixture of two configurational isomers 1a and 1b, which differ from each other in their spatial arrangements of the isopropyl groups at P3 and P4.

引用

页码：1153 / 1157

页数：5

共 23 条

[1] Baudler, 1987, ANGEW CHEM, V99, P429
[2] CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .209. PENTAORGANYLNONAPHOSPHANES(5) WITH A STRUCTURE ANALOGOUS TO NORADAMANTANE - A-P9ET5 AND A-P9(I-PR)5
BAUDLER, M
KOLL, B
ARNDT, V
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1990, 45 (11): : 1517 - 1521
[3] CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .132. P-31 NMR-SPECTRUM AND STRUCTURE OF TRIMETHYLHEPTAPHOSPHANE(3), P7ME3
BAUDLER, M
PONTZEN, T
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1983, 38 (08): : 955 - 960
[4] CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .187. HEXAISOPROPYLDECAPHOSPHANE(6), P10(I-PR)6- PREPARATION AND STRUCTURE DETERMINATION BY P-31-NMR SPECTROSCOPY
BAUDLER, M
SCHLITTE, S
HASENBACH, J
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 560 (05): : 7 - 17
[5] CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .100. PENTAMETHYL-HEPTAPHOSPHANE(5), P7(CH3)5, AND PENTAMETHYL-NONAPHOSPHANE(5), P9(CH3)5
BAUDLER, M
AKTALAY, Y
HAHN, J
DARR, E
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1981, 473 (02): : 20 - 34
[6] BAUDLER M, 1983, Z NATURFORSCH B, V38, P428
[7] BAUDLER M, 1984, Z NATURFORSCH B, V39, P275
[8] CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .118. CHAIN AND RING PHOSPHORUS-COMPOUNDS - ANALOGIES BETWEEN PHOSPHORUS AND CARBON-CHEMISTRY
BAUDLER, M
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1982, 21 (07): : 492 - 512
[9] CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .163. ABOUT THE TRIORGANO-NONAPHOSPHANES(3) P9ET3 AND P9(T-BU)3 - THE 1ST DETECTION OF THE INVERSION OF CONFIGURATION IN A POLYCYCLOPHOSPHANE
BAUDLER, M
HAHN, J
ARNDT, V
KOLL, B
KAZMIERCZAK, K
DARR, E
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1986, 538 (07): : 7 - 20
[10] CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .176. P8IPR4 - THE 1ST TRICYCLO[3.2.1.02,4]OCTAPHOSPHANE
BAUDLER, M
KOLL, B
ADAMEK, C
GLEITER, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (04): : 347 - 348

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