DRIFTS CHAMBER FOR IN-SITU AND SIMULTANEOUS STUDY OF INFRARED AND ELECTRICAL RESPONSE OF SENSORS

被引:15
作者
BENITEZ, JJ
CENTENO, MA
MERDRIGNAC, OM
GUYADER, J
LAURENT, Y
ODRIOZOLA, JA
机构
[1] UNIV SEVILLA,CSIC,INST CIENCIA MAT SEVILLA,E-41071 SEVILLE,SPAIN
[2] UNIV RENNES,CHIM MAT LAB,F-35042 RENNES,FRANCE
关键词
DIFFUSE REFLECTANCE INFRARED SPECTROSCOPY (DRIFTS); OXYNITRIDES; NOX AND NH3 SENSORS;
D O I
10.1366/0003702953965146
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
A diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) chamber suitable for in situ and simultaneous analysis of the infrared and electrical response of sensors is tested and described in detail, Experiments on a CdGeON sensor show some results about its reversible/ irreversible behavior in terms of temperature and under N-2 atmosphere. A direct relationship between the conductivity and the elimination of DRIFTS peaks at 810, 780, and 580 cm(-1) is observed. From both DRIFTS spectra and conductivity measurements, an explanation involving the presence and filling of vacancies in the solid framework is proposed.
引用
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页码:1094 / 1096
页数:3
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