CLEAVAGE OF AN ARYL CARBON-SULFUR BOND IN HYDRIDE-THIOLATE COMPLEXES OF MOLYBDENUM(IV) - X-RAY CRYSTAL-STRUCTURE OF [(MO(SC6H2(PR-ISO)3-2,4,6)(OME)(PMEPH2))2(MU-S)2]

被引：25

作者：

BURROW, TE

HILLS, A

HUGHES, DL

LANE, JD

LAZAROWYCH, NJ

MAGUIRE, MJ

MORRIS, RH

RICHARDS, RL

机构：

[1] AFRC,IPSR,NITROGEN FIXAT LAB,SUSSEX,ENGLAND

[2] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1990年 / 24期

关键词：

D O I：

10.1039/c39900001757

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes [MoH(SC6H2R3-2,4,6)3(PR'Ph2)] 1 (R = Me or Pr(i); R = Me or Et) in THF-MeOH decompose via cleavage of an aryl carbon-sulphur bond to give C6H3-2,4,6 and complexes [{Mo(SC6H2R3-2,4,6)(OMe)(PR'Ph2)}2(mu-S)2], 3, one of which (R = Pr(i), R' = Me) has been characterized by single crystal X-ray diffraction.

引用

页码：1757 / 1759

页数：3

共 17 条

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