THE AZIDE HOMOLOGS ET-PPP AND PH-ASASAS AS BIFACIALLY COORDINATED LIGANDS IN TRIPOD-COBALT COMPLEXES - SYNTHESIS, STRUCTURE AND MOLECULAR-DYNAMICS

被引：40

作者：

BARTH, A ^{[1
]}

HUTTNER, G ^{[1
]}

FRITZ, M ^{[1
]}

ZSOLNAI, L ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,NEUENHEIMER FELD 270,W-6900 HEIDELBERG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 08期

关键词：

D O I：

10.1002/anie.199009291

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

What should they be called, the higher homologues of azides: phosphides and arsides? Hardly, and even the 1990 recommendations of the Inorganic IUPAC rules do not help very much further. Research is often one step ahead of nomenclatural canonization, as is demonstrated by the synthesis of the PhAs3 complex cation 1 and an EtP3 analogue. 1 is formed upon reaction of Co(BF4)2 · 6H2O with PhAsH2 in the presence of H3CC(CH2PPh2)3 (= L) and can be isolated as the BF 4⊖ salt (blackish‐green crystals). (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：929 / 931

页数：3

共 23 条

[1] TRIPLE-DECKER SANDWICH COMPLEXES OF CYCLO-TRIPHOSPHORUS WITH 4D-METALS AND 5D-METALS [J].

BIANCHINI, C ;

DIVAIRA, M ;

MELI, A ;

SACCONI, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (06) :1448-1452

[2] NEW PHOSPHORUS-SULFUR LIGANDS IN CP2MO2PXSY COMPLEXES (X=2,4 Y=5-X) PRODUCED FROM CP2MO2(CO)4 (CP = ETA-5-C5ME5) AND P4S3 [J].

BRUNNER, H ;

KLEMENT, U ;

MEIER, W ;

WACHTER, J ;

SERHADLE, O ;

ZIEGLER, ML .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 335 (03) :339-352

[3]

CAPPOZZI G, 1986, J CHEM SOC CHEM COMM, P1799

[4] CRYSTAL AND MOLECULAR STRUCTURE OF A TRIGONAL FORM OF PHOSPHOBENZENE B (PC6H5)6 [J].

DALY, JJ .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (SEP) :4789-&

[5]

Di Vaira M., 1982, ANGEW CHEM, V94, P338

[6] SYNTHESIS AND CHARACTERIZATION OF DINUCLEAR METAL-COMPLEXES WITH THE P2S AND AS2S HETEROATOMIC INORGANIC RINGS AS BRIDGING UNITS - CRYSTAL AND MOLECULAR-STRUCTURE OF [(TRIPHOS)RH(AS2S)RH(TRIPHOS)](BPH4)2.2(CH3)2CO[TRIPHOS=1,1,1-TRIS((DIPHENYLPHOSPHINO)METHYL)ETHANE] [J].

DIVAIRA, M ;

MANI, F ;

MONETI, S ;

PERUZZINI, M ;

SACCONI, L ;

STOPPIONI, P .

INORGANIC CHEMISTRY, 1985, 24 (14) :2230-2236

[7] CYCLO-TRIPHOSPHORUS (DELTA-P3) AS A LIGAND IN COBALT AND NICKEL-COMPLEXES WITH 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE - FORMATION AND STRUCTURES [J].

DIVAIRA, M ;

GHILARDI, CA ;

MIDOLLINI, S ;

SACCONI, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (08) :2550-2551

[8]

DIVAIRA M, 1982, ANGEW CHEM INT EDIT, V21, P330

[9] ADDITION AND SUBSTITUTION-REACTIONS OF FE(CO)3[FE(CO)3+CH+CPH+S] [J].

FASSLER, T ;

HUTTNER, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 381 (03) :391-408

[10] 6-VERTEX AND 5-VERTEX ORGANOMETALLIC CLUSTERS [J].

HALET, JF ;

HOFFMANN, R ;

SAILLARD, JY .

INORGANIC CHEMISTRY, 1985, 24 (11) :1695-1700

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