SYNTHESIS AND STEREOCHEMICAL ASSIGNMENTS FOR GONIOBUTENOLIDE-A AND GONIOBUTENOLIDE-B

被引：41

作者：

XU, DQ ^{[1
]}

SHARPLESS, KB ^{[1
]}

机构：

[1] Scripps Res Inst, DEPT CHEM, LA JOLLA, CA 92037 USA

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 27期

关键词：

D O I：

10.1016/S0040-4039(00)76941-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Goniobutenolides A and B and their C-7 epimers are stereoselectively synthesized using osmium-catalyzed asymmetric dihydroxylation (AD) as the key transformation. The relative and absolute stereochemistry gf the natural goniobutenolides A and B are assigned with reference to the spectral data and optical rotations from the literature.

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页码：4685 / 4688

页数：4

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