CHEMILUMINESCENT REACTIONS STUDIED BY LASER ABLATION - DETECTION OF ALO (B2-SIGMA+) IN THE AL+O2 SYSTEM

被引:17
作者
KASATANI, K [1 ]
HIGASHIDE, H [1 ]
SHINOHARA, H [1 ]
SATO, H [1 ]
机构
[1] MIE UNIV,FAC ENGN,DEPT CHEM RESOURCES,TSU,MIE 514,JAPAN
关键词
D O I
10.1016/0009-2614(90)85328-A
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The chemiluminescent reaction between Al atoms produced by pulsed laser ablation and O2 molecules has been studied. The blue-green emission observed is assigned to the AlO B→X transition. The vibrational distribution of AlO B state is describable as a Boltzmann distribution at 4500 ± 300 K. A mechanism for production of the AlO B state via an AlO3 intermediate is proposed. © 1990.
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页码:71 / 74
页数:4
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