SYNTHESIS AND SOLVOLYSIS OF 1-BROMOBICYCLO[1.1.1]PENTANE

被引：35

作者：

DELLA, EW

TAYLOR, DK

机构：

[1] School of Physical Sciences, Flinders University of South Australia, SA, 5042, Bedford Park

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1990年 / 43卷 / 05期

关键词：

D O I：

10.1071/CH9900945

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1-Bromobicyclo[1.1.1]pentane (3) is found to undergo solvolysis faster than t-butyl bromide in 80% aqueous ethanol, and gives 3-methylenecyclobutanol (7) exclusively. Products arising from capture of the bicyclo[1.1.1] pentyl cation (5) were not detected. © 1990 ASEG.

引用

页码：945 / 948

页数：4

共 11 条

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