A STUDY OF MIXTURES OF POLY(ETHYLENE OXIDE) WITH POLYSTYRENE OR POLY(STYRENE-CO-ACRYLIC ACID) BY INVERSE GAS-CHROMATOGRAPHY AND VISCOSIMETRY

被引：6

作者：

CHERRAK, DE ^{[1
]}

DJADOUN, S ^{[1
]}

机构：

[1] UNIV SCI & TECHNOL HOUARI BOUMEDIENE, INST CHEM, BP 32 EL ALIA, ALGIERS, ALGERIA

来源：

POLYMER BULLETIN | 1991年 / 27卷 / 03期

关键词：

D O I：

10.1007/BF00294534

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Systems of poly(ethylene oxide)/polystyrene and of poly(ethylene oxide)/poly(styrene-co-acrylic acid) of different ratios were studied by inverse gas chromatography using benzene and n-decane as molecule probes and by viscosimetry in tetrahydrofuran. The transition temperatures as shown in the retention diagrams and the interaction parameters as determined by inverse gas chromatography and by viscosimetry showed that whereas poly(ethylene oxide) is incompatible with polystyrene, the introduction of amounts of acrylic acid groups into polystyrene chains by free radical copolymerization led to compatible systems of the acidic copolymer with the poly(ethylene oxide).

引用

页码：289 / 295

页数：7

共 20 条

[1]

CHERRAK DE, UNPUB

[2] THERMODYNAMIC INTERACTIONS IN POLYMER SYSTEMS BY GAS-LIQUID-CHROMATOGRAPHY .4. INTERACTIONS BETWEEN COMPONENTS IN A MIXED STATIONARY PHASE [J].

DESHPAND.DD ;

PATTERSO.D ;

SCHREIBE.HP ;

SU, CS .

MACROMOLECULES, 1974, 7 (04) :530-535

[3] PARTIAL MOLAR HEATS OF MIXING OF SMALL MOLECULES WITH POLYMERS BY GAS-CHROMATOGRAPHY [J].

DIPAOLABARANYI, G ;

BRAUN, JM ;

GUILLET, JE .

MACROMOLECULES, 1978, 11 (01) :224-227

[4]

DIPAOLABARANYI G, 1988, P ACS DIV POLYM MAT, V58, P735

[5]

DIPAOLABARANYI G, 1980, MACROMOLECULES, V14, P683

[6]

DIPAOLABARANYI G, 1989, ACS SYM SER, V391, P109

[7]

ELORZA JM, 1988, MAKROMOL CHEM, V189, P1855

[8]

Fox TG, 1956, B AM PHYS SOC, V1, P123

[9] GAS-CHROMATOGRAPHIC STUDY OF THE INTERACTIONS IN STYRENE-DIMETHYLSILOXANE BLOCK COPOLYMERS AND BLENDS [J].

GALIN, M ;

RUPPRECHT, MC .

MACROMOLECULES, 1979, 12 (03) :506-511

[10] GAS-CHROMATOGRAPHIC INVESTIGATION OF THERMODYNAMIC INTERACTIONS OF POLY(DIMETHYLSILOXANE) OR POLY(DIETHYLSILOXANE) WITH SOME SOLVENTS BETWEEN 60-DEGREES-C AND 180-DEGREES-C [J].

GALIN, M .

MACROMOLECULES, 1977, 10 (06) :1239-1244

← 1 2 →