EFFECT OF COMPOSITION AND SIZE OF CRYSTALLITE ON CRYSTAL PHASE IN LEAD BARIUM-TITANATE

被引：48

作者：

SAEGUSA, K ^{[1
]}

RHINE, WE ^{[1
]}

BOWEN, HK ^{[1
]}

机构：

[1] MIT,CERAM PROC RES LAB,CAMBRIDGE,MA 02139

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 1993年 / 76卷 / 06期

关键词：

D O I：

10.1111/j.1151-2916.1993.tb03932.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Lead titanate, barium titanate, and lead barium titanate powders (>99.9% pure), the particle size of which varied from 0.03 to 0.15 mum depending on the calcination temperature and the composition, was-prepared from barium lead titanyl oxalate, which was previously prepared by reacting high-purity ammonium titanyl oxalate with barium and lead acetate. The critical crystallite size of BaTiO3 powder from the cubic to the tetragonal phase is around 1 mum. Pb0.3Ba0.7TiO3 powder with an average size of 0.057 mum showed the tetragonal phase.

引用

页码：1505 / 1512

页数：8

共 24 条

[1]

Art G., 1985, J APPL PHYS, V58, P1619

[2]

Barin I., 2013, THERMOCHEMICAL PROPE

[3]

Barin I., 1989, THERMOCHEMICAL DATA, Vthird

[4]

BELL AJ, 1984, FERROELECTRICS, V55, P147

[5]

BELLOSI L, 1985, PARAGONE, V36, P57

[6] PHENOMENOLOGICAL THEORY OF HIGH PERMITTIVITY IN FINE-GRAINED BARIUM TITANATE [J].

BUESSEM, WR ;

CROSS, LE ;

GOSWAMI, AK .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1966, 49 (01) :33-&

[7]

BULAEVSKII LN, 1964, FIZ TVERD TELA, V5, P2329

[8] PREPARATION OF BARIUM TITANYL OXALATE TETRAHYDRATE FOR CONVERSION TO BARIUM TITANATE OF HIGH PURITY [J].

CLABAUGH, WS ;

SWIGGARD, EM ;

GILCHRIST, R .

JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS, 1956, 56 (05) :289-291

[9] EFFECTS OF CRYSTALLITE SIZE IN PBTIO3 THIN-FILMS [J].

DEKEIJSER, M ;

DORMANS, GJM ;

VANVELDHOVEN, PJ ;

DELEEUW, DM .

APPLIED PHYSICS LETTERS, 1991, 59 (27) :3556-3558

[10] SIZE EFFECT ON THE FERROELECTRIC PHASE-TRANSITION IN PBTIO3 ULTRAFINE PARTICLES [J].

ISHIKAWA, K ;

YOSHIKAWA, K ;

OKADA, N .

PHYSICAL REVIEW B, 1988, 37 (10) :5852-5855

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