SYNTHESIS OF A NEW FAMILY OF PHENOL RESIN BY ENZYMATIC OXIDATIVE POLYMERIZATION

被引：97

作者：

UYAMA, H ^{[1
]}

KURIOKA, H ^{[1
]}

KANEKO, I ^{[1
]}

KOBAYASHI, S ^{[1
]}

机构：

[1] TOHOKU UNIV, FAC ENGN, DEPT MOLEC CHEM & ENGN, AOBA KU, SENDAI, MIYAGI 980, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 03期

关键词：

D O I：

10.1246/cl.1994.423

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enzymatic oxidative polymerization of phenol has been performed in an aqueous organic solvent using horseradish peroxidase as catalyst to produce a new family of phenol resin. The resulting polymer was partly soluble in DMF and DMSO and the fraction soluble in DMF has molecular weight of 3.5x10(4). From IR and H-1 NMR analyses, the polymer structure was found to be composed of a mixture of phenylene and oxyphenylene units.

引用

页码：423 / 426

页数：4

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