6,7-BIS(METHOXYCARBONYL)-2,3-DIMETHYL-[5](1,4)NAPHTHALENOPHANE, THE FIRST BENZOANNELATED [5]PARACYCLOPHANE

被引：17

作者：

VANES, DS ^{[1
]}

DEKANTER, FJJ ^{[1
]}

DEWOLF, WH ^{[1
]}

BICKELHAUPT, F ^{[1
]}

机构：

[1] FREE UNIV AMSTERDAM,SCHEIKUNDIG LAB,1081 HV AMSTERDAM,NETHERLANDS

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 22期

关键词：

CYCLOPHANES; DEWAR NAPHTHALENE; PHOTOCHEMISTRY; STRAINED RINGS;

D O I：

10.1002/anie.199525531

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound 2 forms 35% of the photodynamic equilibrium mixture with its precursor 1. Compound 2 is the smallest known [n](1,4)naphthalenophane and the most stable derivative of [5]paracyclophane known to date. Compound 1 was obtained in five steps from the Dewar benzene 3. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2553 / 2555

页数：3

共 14 条

[1]

BALDEW AU, 1993, THESIS VRIJE U

[2]

BICKELHAUPT F, 1990, PURE APPL CHEM, V62, P37

[3]

Bickelhaupt F., 1993, ADV STR ORG, V3, P185

[4]

FREIERMUTH B, 1985, CHIMIA, V39, P22

[5] SYNTHESIS OF DOUBLY BRIDGED PRISMANES - AN INVESTIGATION OF THE PHOTOCHEMICAL BEHAVIOR OF DOUBLY BRIDGED DEWAR BENZENES [J].

GLEITER, R ;

TREPTOW, B .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (27) :7740-7750

[6] [5]PARACYCLOPHANE [J].

JENNESKENS, LW ;

DEKANTER, FJJ ;

KRAAKMAN, PA ;

TURKENBURG, LAM ;

KOOLHAAS, WE ;

DEWOLF, WH ;

BICKELHAUPT, F ;

TOBE, Y ;

KAKIUCHI, K ;

ODAIRA, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (12) :3716-3717

[7]

JENNESKENS LW, 1986, THESIS VRIJE U

[8] INTERCONVERSION OF [6]PARACYCLOPHANE AND 1,4-HEXAMETHYLENE(DEWAR BENZENE) [J].

KAMMULA, SL ;

IROFF, LD ;

JONES, M ;

VANSTRATEN, JW ;

WOLF, WHD ;

BICKELHAUPT, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (17) :5815-5815

[9] [6]PARACYCLOPHANE [J].

KANE, VV ;

WOLF, AD ;

JONES, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (08) :2643-2644

[10] STABILIZATION OF (5)PARACYCLOPHANES VIA BENZENE-RING SUBSTITUTION [J].

KOSTERMANS, GBM ;

DEWOLF, WH ;

BICKELHAUPT, F .

TETRAHEDRON, 1987, 43 (13) :2955-2966

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