MECHANISM OF SULFUR EXTRUSION IN 2,2 DICHLORO-3-[9-FLUORENYL] EPISULFIDE

被引：14

作者：

CHEW, W ^{[1
]}

HARPP, DN ^{[1
]}

机构：

[1] MCGILL UNIV,DEPT CHEM,MONTREAL H3A 2K6,QUEBEC,CANADA

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 01期

关键词：

D O I：

10.1016/S0040-4039(00)77669-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,2 Dichloro-3-[9-fluorenyl] episulfide (2) slowly extrudes sulfur when treated thermally. The reaction generally follows unimolecular behavior but at higher concentrations in decalin, toluene and p-xylene, a bimolecular pathway is demonstrated. Kinetic and mechanistic aspects are discussed.

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页码：45 / 48

页数：4

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