A STEREOSELECTIVE TOTAL SYNTHESIS OF (PLUS-OR-MINUS)-ERYTHRODIENE

被引：19

作者：

HUANG, H ^{[1
]}

FORSYTH, CJ ^{[1
]}

机构：

[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 49期

关键词：

D O I：

10.1016/S0040-4039(00)61502-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Erythrodiene, a unique spirobicyclic sesquiterpene hydrocarbon from the Caribbean gorgonian cord Erythropodium caribaeorum, has been synthesized from 4-isopropylcyclohexanol in 8-steps and approximately 16% overall yield. The synthesis features a stereoselective intramolecular carbomercuration reaction as the key step.

引用

页码：7889 / 7890

页数：2

共 8 条

[1]

ALDERDICE M, 1990, ORG SYNTH, V7, P351

[2] SESQUITERPENOIDS .64. .143. SPIROJATAMOL, A NEW SKELETAL SESQUITERPENOID OF NARDOSTACHYS-JATAMANSI ROOTS [J].