CALCULATION OF PROGRAMMED-TEMPERATURE GAS-CHROMATOGRAPHY CHARACTERISTICS FROM ISOTHERMAL DATA .5. PREDICTION OF PEAK ASYMMETRIES AND RESOLUTION CHARACTERISTICS

被引：12

作者：

ALBAJJARI, TI ^{[1
]}

LEVENT, S ^{[1
]}

TAYLOR, DR ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

JOURNAL OF CHROMATOGRAPHY A | 1994年 / 683卷 / 02期

关键词：

D O I：

10.1016/0021-9673(94)00332-7

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

A previously described procedure for the calculation of peak widths in programmed temperature gas chromatograms from corresponding isothermal widths has been adapted to the analogous calculation of peak asymmetries. Comparison with experimental data is satisfactory. Composite predictions of retention times, widths and asymmetries are then used to predict (a) the forms of complete chromatograms comprising close peaks, (b) resolution characteristics of such chromatograms and (c) optimum programmed temperature conditions.

引用

页码：377 / 384

页数：8

共 10 条

[1]

AKHPORHONOR EE, 1990, J CHROMATOGR, V504, P269

[2]

AKHPORHONOR EE, 1989, J CHROMATOGR, V463, P271

[3]

AKHPORHONOR EE, 1987, J CHROMATOGR, V405, P67

[4]

ALBAJJARI TA, 1990, THESIS U MANCHESTER

[5] CALCULATION OF PROGRAMMED-TEMPERATURE GAS-CHROMATOGRAPHY CHARACTERISTICS FROM ISOTHERMAL DATA .4. PREDICTION OF PEAK WIDTHS [J].

ALBAJJARI, TI ;

LEVENT, S ;

TAYLOR, DR .

JOURNAL OF CHROMATOGRAPHY A, 1994, 683 (02) :367-376

[6]

PAULS RE, 1977, ANAL CHEM, V49, P625, DOI 10.1021/ac50012a030

[7] OPTIMIZATION OF BASIC PARAMETERS IN TEMPERATURE-PROGRAMMED GAS-CHROMATOGRAPHIC SEPARATIONS OF MULTI-COMPONENT SAMPLES WITHIN A GIVEN TIME [J].

REPKA, D ;

KRUPCIK, J ;

BRUNOVSKA, A ;

LECLERCQ, PA ;

RIJKS, JA .

JOURNAL OF CHROMATOGRAPHY, 1989, 463 (02) :235-242

[8]

SCHOENMAKER SPJ, 1986, J CHROMATOGRAPHY LIB, V35, P116

[9] CORRECTION OF THE RESOLUTION FUNCTION FOR NON-IDEAL PEAKS [J].

SCHOENMAKERS, PJ ;

STRASTERS, JK ;

BARTHA, A .

JOURNAL OF CHROMATOGRAPHY, 1988, 458 :355-370

[10]

SCHOENMAKERS PJ, 1986, J CHROMATOGRAPHY LIB, V35

← 1 →