THE EFFECTS OF HYDRATION ON THE LUMINESCENCE SPECTRA OF TRISODIUM TRIS(2,6-PYRIDINEDICARBOXYLATO)EUROPIUM(III) COMPOUNDS

被引：45

作者：

MURRAY, GM

SARRIO, RV

PETERSON, JR

机构：

[1] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996

[2] OAK RIDGE NATL LAB,DIV CHEM,TRANSURANIUM RES LAB,OAK RIDGE,TN 37831

来源：

INORGANICA CHIMICA ACTA | 1990年 / 176卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)84849-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Luminescence spectra of the hydrated and anhydrous salts of trisodium tris(2,6-pyridinedicarboxylato)europium(III) compounds have been measured at high resolution (better than 1.0 cm-1) and at low temperature (77 K). The alterations in the crystal field splittings, linewidths and relative intensities, as produced by the influence of crystal hydration, are examined and are discussed in detail.

引用

页码：233 / 240

页数：8

共 14 条

[1] STRUCTURAL STUDIES ON RARE-EARTH CARBOXYLATES .12. CRYSTAL AND MOLECULAR STRUCTURE OF TRICLINIC TRISODIUM TRIS-(PYRIDINE-2,6-DICARBOXYLATO)NEODYMATE(III) 15-HYDRATE [J].