WEAK TERNARY CT SALTS FORMED BY ALPHA-KEGGIN POLYANIONS AND TETRAPHENYLPORPHYRINATO ZN(II) IN THE PRESENCE OF HALIDE-IONS

被引：24

作者：

ATTANASIO, D ^{[1
]}

BACHECHI, F ^{[1
]}

机构：

[1] CNR,IST STRUTTURIST CHIM G GIACOMELLO,I-00016 MONTEROTONDO,ITALY

来源：

ADVANCED MATERIALS | 1994年 / 6卷 / 02期

关键词：

D O I：

10.1002/adma.19940060210

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular complexes between alpha-Keggin polyanions and tetraphenylporphyrinato Zn(II) are unexpectedly stable have been obtained in the presence of an ancillary donor anion such as a halide. X-ray structure determination reveals integrated organic-inorganic stacks with alkyl ammonium cations acting as spacers. Development of these compounds, which combine thermally and photochemically redox active units, may lead to molecular materials with interesting electro- and photochromic properties.

引用

页码：145 / 147

页数：3

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