ANALYTICAL MULTIMETHOD FOR THE DETERMINATION OF LOW VOLATILE ORGANIC POLLUTANTS IN SEDIMENTS AND SEWAGE SLUDGES

被引：25

作者：

KOLB, M ^{[1
]}

BOHM, HB ^{[1
]}

BAHADIR, M ^{[1
]}

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ECOL CHEM & WASTE ANAL,D-38106 BRAUNSCHWEIG,GERMANY

来源：

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1995年 / 351卷 / 2-3期

关键词：

D O I：

10.1007/BF00321650

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

By means of selected target compounds with different physical and chemical properties an analytical method has been developed for the analysis of a wide variety of low volatile xenobiotics in sediments and sewage sludges. After an exhaustive extraction at different pH values first high molecular matrix compounds have been separated by GPC. Fractionation of the samples into five separate groups of substances has been performed by successive column chromatography using deactivated alumina and silica gel. For the determination of phenols a derivatization step with pentafluorobenzoylchloride has been incorporated into the sample preparation. Removal of sulphur and aliphatic hydrocarbons has been accomplished by an additional clean up with TBA-sulfite reagent and silica gel. Recoveries of the most target compounds exceeded 80%.

引用

页码：286 / 296

页数：11

共 36 条

[1]

BEDDING ND, 1988, J CHROMATOGR SCI, V23, P597

[2] REMOVAL OF ELEMENTAL SULFUR FROM HYDROCARBON FRACTIONS [J].

BLUMER, M .

ANALYTICAL CHEMISTRY, 1957, 29 (07) :1039-1041

[3]

BOHM HB, 1993, THESIS TU BRAUNSCHWE

[4] SEDIMENTATION OF 74-PCB CONGENERS IN THE UPPER HUDSON RIVER [J].

BUSH, B ;

SHANE, LA ;

WAHLEN, M ;

BROWN, MP .

CHEMOSPHERE, 1987, 16 (04) :733-744

[5] CHLORINATED HYDROCARBONS IN SEDIMENTS OF THE ELBE RIVER AND THE ELBE ESTUARY [J].

EDER, G ;

STURM, R ;

ERNST, W .

CHEMOSPHERE, 1987, 16 (10-12) :2487-2496

[6] NOTE ON REMOVAL OF SULFUR INTERFERENCES FROM SEDIMENT EXTRACTS FOR PESTICIDE ANALYSIS [J].

GOERLITZ, DF ;

LAW, LM .

BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY, 1971, 6 (01) :9-&

[7] ANALYSIS OF POLYCYCLIC AROMATIC-HYDROCARBONS IN SEDIMENTS, SEWAGE SLUDGES AND COMPOSTS FROM MUNICIPAL REFUSE BY HPLC [J].

HAGENMAIER, H ;

KAUT, H ;

KRAUSS, P .

INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 1986, 23 (04) :331-345

[8]

HAILE CL, 1984, EPA600484001 REP, P296

[9] POLYCYCLIC AROMATIC-HYDROCARBONS IN SEDIMENTS OF THE SOUTHERN BASIN OF LAKE-MICHIGAN [J].

HELFRICH, J ;

ARMSTRONG, DE .

JOURNAL OF GREAT LAKES RESEARCH, 1986, 12 (03) :192-199

[10] COMPARISON OF EXTRACTION METHODS FOR POLYCYCLIC AROMATIC HYDROCARBON DETERMINATION IN SEDIMENTS [J].

HOLOUBEK, I ;

PAASIVIRTA, J ;

MAATELA, P ;

LAHTIPERA, M ;

HOLOUBKOVA, I ;

KORINEK, P ;

BOHACEK, Z ;

CASLAVSKY, J .

TOXICOLOGICAL AND ENVIRONMENTAL CHEMISTRY, 1990, 25 (2-3) :137-154

← 1 2 3 4 →