Degradation of four pharmaceuticals by solar photo-Fenton process: Kinetics and costs estimation

被引：211

作者：

Alalm, Mohamed Gar ^{[1
]}

Tawfik, Ahmed ^{[1
]}

Ookawara, Shinichi ^{[2
]}

机构：

[1] Egypt Japan Univ Sci & Technol E Just, Sch Energy Environm & Proc Engn, Alexandria 21934, Egypt

[2] Tokyo Inst Technol, Dept Chem Engn, Grad Sch Sci & Engn, Meguro Ku, Tokyo 1528552, Japan

来源：

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING | 2015年 / 3卷 / 01期

关键词：

Compound parabolic collectors; Pharmaceuticals; Photo-Fenton; Solar;

D O I：

10.1016/j.jece.2014.12.009

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 [工学]; 0830 [环境科学与工程];

摘要：

Solar photo-Fenton process for degradation of four types of pharmaceuticals namely amoxicillin, ampicillin, diclofenac, and paracetamol was studied. Experiments were carried out by solar compound parabolic collectors (CPCs) reactor with borosilicate tubes and capacity of 4.0 L. Oxidation of each pharmaceutical was investigated individually using 100 mg/L synthetic solution. The influence of irradiation time, initial pH value, and dosage of Fenton reagent were investigated. Paracetamol, and amoxicillin were completely removed after 60 and 90 min of irradiation respectively. Complete degradation of ampicillin and diclofenac was occurred after 120 min. The removal of pharmaceuticals was significantly affected by changing pH values from 3 to 10. Complete removal of all pharmaceuticals was achieved under acidic conditions (pH 3). The optimum H2O2 and FeSO4.7H(2)O dosage were 1.5 and 0.5 g/L, respectively. The results of photo-Fenton experiments fitted the pseudo-first order kinetic equation with high correlation. Costs estimation of 30m(3)/d full scale solar photo-oxidation plant was assessed. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：46 / 51

页数：6

共 42 条

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Influence of parameters on the heterogeneous photocatalytic degradation of pesticides and phenolic contaminants in wastewater: A short review [J].