A CONVENIENT METHODOLOGY FOR THE SELECTIVE REDUCTION OF CARBOXYLIC-ACIDS WITH BENZYLTRIETHYL-AMMONIUM BOROHYDRIDE - CHLOROTRIMETHYLSILANE

被引：20

作者：

DAS, J ^{[1
]}

CHANDRASEKARAN, S ^{[1
]}

机构：

[1] INDIAN INST SCI,DEPT ORGAN CHEM,BANGALORE 560012,KARNATAKA,INDIA

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 06期

关键词：

D O I：

10.1080/00397919008052339

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A combination of benzyltriethylammonium borohydride and chlorotrimethylsilane (1:1) in dichloromethane (0-25°C) has been found to be a convenient reagent system for the selective reduction of carboxylic acids to alcohols. Copyright © 1990 by Taylor & Francis Group. All rights reserved.

引用

页码：907 / 912

页数：6

共 16 条

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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (06) : 1014 - 1016
[5] LIBH4(NABH4) ME3SICL, AN UNUSUALLY STRONG AND VERSATILE REDUCING AGENT
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SANDHOFF, K
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (02): : 218 - 220
[6] HAJOS A, 1981, METHOD ORGAN CHEM, V4, P1
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[9] KANO S, 1980, SYNTHESIS-STUTTGART, P695
[10] FORMATION OF ALCOHOLS FROM ALKENES BY REACTION WITH SNCL4-NABH4
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (18) : 796 - 796

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