SYNTHESIS OF FERROELECTRIC PEROVSKITES THROUGH AQUEOUS-SOLUTION TECHNIQUES

被引：12

作者：

GUZMAN, G ^{[1
]}

AEGERTER, MA ^{[1
]}

BARBOUX, P ^{[1
]}

LIVAGE, J ^{[1
]}

机构：

[1] UNIV P & M CURIE,CNRS,F-75252 PARIS 05,FRANCE

来源：

JOURNAL OF MATERIALS SCIENCE | 1993年 / 28卷 / 23期

关键词：

D O I：

10.1007/BF01352222

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The hydrolysis of niobates in aqueous solutions has been applied to the coprecipitation of PbNb2/3Mg1/303 leading to a low temperature synthesis of this ferroelectric relaxor ceramic. The effect of hydrolysis conditions - such as the concentration of bases and acids used, their rates of addition and the nature of the precursors salts - is described. The perovskite phase appears after heating at 350-degrees-C and is obtained as a pure phase at 800-degrees-C after heat treatment for 1 h. Relaxor ferroelectric ceramics with a high dielectric constant can be obtained by sintering at 1000-degrees-C. The process has been also applied to the synthesis of other relaxor ceramic compositions such as PZN (PbNb2/3Zn1/303) and PFN (PbNb1/2Fe1/203) compounds.

引用

页码：6510 / 6515

页数：6

共 16 条

[1]

ANDERSON HU, 1987, ADV CERAM CERAM POWD, V21, P61

[2]

[Anonymous], [No title captured], Patent No. [3.330.697, 3330697]

[3]

GOLUB AM, 1969, RUSSIAN J INORG CEHM, V14, P607

[4]

GOO E, 1986, J AM CERAM SOC, V69, P188

[5]

HALLIYAL A, 1987, AM CERAM SOC BULL, V66, P671

[6]

HOROWITZ HS, 1988, J AM CERAM SOC, V71, P71

[7] ON STRUCTURES OF DOMINATING HYDROLYSIS PRODUCTS OF LEAD(2) IN SOLUTION [J].

JOHANSSON, G ;

OLIN, A .

ACTA CHEMICA SCANDINAVICA, 1968, 22 (10) :3197-+

[8]

Lejeune M., 1982, Ceramics International, V8, P99, DOI 10.1016/0272-8842(82)90025-6

[9]

LEJEUNE M, 1984, FERROELECTRICS, V54, P191

[10]

LESSING PA, 1989, AM CERAM SOC BULL, V68, P1002

← 1 2 →