HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY USING CONTINUOUS ONLINE POST-ELUTION PHOTOIRRADIATION WITH SUBSEQUENT DIODE-ARRAY UV OR THERMOSPRAY MASS-SPECTROMETRY DETECTION

被引：26

作者：

LURIE, IS

COOPER, DA

KRULL, IS

机构：

[1] NORTHEASTERN UNIV,DEPT CHEM,BOSTON,MA 02115

[2] NORTHEASTERN UNIV,BARNETT INST CHEM ANAL,BOSTON,MA 02115

来源：

JOURNAL OF CHROMATOGRAPHY | 1993年 / 629卷 / 02期

关键词：

D O I：

10.1016/0021-9673(93)87029-L

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The use of HPLC with continuous on-line post-elution photoirradiation followed by either diode-array UV or thermospray mass spectrometric detection is presented. These tandem techniques can greatly increase specificity of analysis, as demonstrated by select compounds whose UV or thermospray mass spectra are highly similar under lamp off conditions but significantly different after photoirradiation. The utility of the above approach for various compounds of forensic interest is presented.

引用

页码：143 / 151

页数：9

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[3]

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