CROSS-LINKING OF VINYL ESTER MATRIX IN CONTACT WITH DIFFERENT SURFACES

被引：22

作者：

DIRAND, X ^{[1
]}

HILAIRE, B ^{[1
]}

LAFONTAINE, E ^{[1
]}

MORTAIGNE, B ^{[1
]}

NARDIN, M ^{[1
]}

机构：

[1] CNRS,CTR RECH PHYS CHIM SURFACES SOLIDES,F-68200 MULHOUSE,FRANCE

来源：

COMPOSITES | 1994年 / 25卷 / 07期

关键词：

INTERFACE; INTERPHASE; VINYL ESTER RESIN; SURFACE PROPERTIES; MATRIX STRUCTURE; FTIR; C-13; NMR;

D O I：

10.1016/0010-4361(94)90197-X

中图分类号：

TB33 [复合材料];

学科分类号：

摘要：

This study deals with the physical and chemical analysis of interfaces and interphases in glass/vinyl ester resin systems. The surface of the difference composite components was first analysed by wettability techniques. Matrix was then deposited on different unsized and sized glass substrates, and structural modification of the matrix near the surface of these substrates was studied by means of microscopical Fourier transform infra-red spectroscopy and solid-state C-13 nuclear magnetic resonance. Both techniques clearly showed that the resin network is strongly affected in all cases, leading to the existence of thick interphases. The different phenomena that could be responsible for the existence of such interphases are discussed.

引用

页码：645 / 652

页数：8

共 12 条

[1] DIRAND X, 1993, 93R048 DGA ETCA CREA
[2] DIRAND X, 1990, DIPLOME ETUDE APPROF
[3] Dupre A., 1869, THEORIE MECANIQUE CH
[4] STRUCTURE OF VINYLESTER NETWORKS - A RUBBER ELASTICITY STUDY
GANEM, M
LAFONTAINE, E
MORTAIGNE, B
BELLENGER, V
VERDU, J
[J]. JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1994, B33 (02): : 155 - 172
[5] INVESTIGATION OF THE INTERPHASE OF A SILANE-FINISHED GLASS FIBRE/VINYLESTER RESIN USING A MICROSCOPIC FTIR SPECTROMETER
IKUTA, N
SUZUKI, Y
MAEKAWA, Z
HAMADA, H
[J]. POLYMER, 1993, 34 (11) : 2445 - 2446
[6] JAYARAMAN K, 1993, J COMPOS TECH RES, V15, P3, DOI 10.1520/CTR10348J
[7] LAUMIKITIS MB, 1982, HDB COMPOSITES, V3, P38
[8] LEHUY HM, 1990, THESIS ECOLE NATIONA
[9] Patrick R. L., 1967, TREATISE ADHESION AD, V1, P325
[10] Wu S., 1982, POLYM INTERFACE ADHE

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