A NOVEL TECHNIQUE FOR THE PREPARATION OF METAL-CLUSTERS IN DIELECTRIC MATRICES

被引：12

作者：

LAMBER, R ^{[1
]}

BAALMANN, A ^{[1
]}

JAEGER, NI ^{[1
]}

SCHULZEKLOFF, G ^{[1
]}

WETJEN, S ^{[1
]}

机构：

[1] FRAUNHOFER INST ANGEW MAT FORSCH,D-28717 BREMEN,GERMANY

来源：

ADVANCED MATERIALS | 1994年 / 6卷 / 03期

关键词：

D O I：

10.1002/adma.19940060308

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal clusters trapped in solid‐state matrices can be produced in various wayas. The new method presented here relies on the simultaneous plasma polymerization of a vinyltrimethylsilane monomer and deposition of metal clusters (e.g., Au, Ag, Pd) by an inert gas evaporation technique. The characterization by TEM, XPS, and UV‐vis and FTIR spectroscopy of amonorphous plasma‐polymer films containing gold clusters is described, which revelas that the clusters areunigorm in size and crystalline. Copyright © 1994 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：223 / 225

页数：3

共 15 条

[1] OPTICAL-PROPERTIES OF SILVER MICRO-CRYSTALS PREPARED BY MEANS OF THE GAS AGGREGATION TECHNIQUE [J].

ABE, H ;

SCHULZE, W ;

TESCHE, B .

CHEMICAL PHYSICS, 1980, 47 (01) :95-104

[2] THE ORIGINS OF PARTICLE-SIZE EFFECTS IN HETEROGENEOUS CATALYSIS [J].

BOND, GC .

SURFACE SCIENCE, 1985, 156 (JUN) :966-981

[3] UNSUPPORTED SMALL METAL PARTICLES - PREPARATION, REACTIVITY, AND CHARACTERIZATION [J].

DAVIS, SC ;

KLABUNDE, KJ .

CHEMICAL REVIEWS, 1982, 82 (02) :153-208

[4] THE PHYSICS OF SIMPLE METAL-CLUSTERS - EXPERIMENTAL ASPECTS AND SIMPLE-MODELS [J].

DEHEER, WA .

REVIEWS OF MODERN PHYSICS, 1993, 65 (03) :611-676

[5]

GALLEZOT P, 1986, METAL CLUSTERS, P219

[6] PHYSICS OF MICROCLUSTERS [J].

HALICIOGLU, T ;

BAUSCHLICHER, CW .

REPORTS ON PROGRESS IN PHYSICS, 1988, 51 (06) :883-921

[7] QUANTUM SIZE EFFECTS IN METAL PARTICLES [J].

HALPERIN, WP .

REVIEWS OF MODERN PHYSICS, 1986, 58 (03) :533-606

[8] INCORPORATION OF METALS INTO FLUOROPOLYMER FILMS SYNTHESIZED BY PLASMA TECHNIQUES [J].

KAY, E ;

DILKS, A ;

HETZLER, U .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1978, A12 (09) :1393-1398

[9] BONDING STRUCTURE IN PLASMA-POLYMERIZED FILMS OF VINYLTRIMETHYLSILAN [J].

KRUSE, A ;

HENNECKE, M ;

BAALMANN, A ;

SCHLETT, V ;

STUKE, H .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1991, 95 (11) :1376-1380

[10] ELECTRON-MICROSCOPY STUDY OF THE INTERACTION OF NI, PD AND PT WITH CARBON .3. FORMATION OF A SUBSTITUTIONAL PT-C CARBIDE IN ULTRAFINE PLATINUM PARTICLES [J].

LAMBER, R ;

JAEGER, NI .

SURFACE SCIENCE, 1993, 289 (03) :247-254

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