DIYNE COORDINATION CHEMISTRY - REACTIONS OF [RUCLH(CO)(PPH3)3] WITH DIPHENYLBUTADIYNE AND BIS(PHENYLETHYNYL)MERCURY

被引：62

作者：

HILL, AF

MELLING, RP

机构：

[1] Department of Chemistry, University of Warwick, Coventry

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 396卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)85205-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the hydridometal complex [RuClH(CO)(PPh3)3] with 1,4-diphenyl-butadi-1,3-yne has been investigated and found to proceed with monoinsertion to give a coordinatively unsaturated σ-vinyl complex [Ru-{C(CCPh)CHPh} Cl(CO)(PPh3)2], which is also the major product of the reaction of [RuClH(CO) (PPh3)3] with [Hg(CCPh)2]. © 1990.

引用

页码：C22 / C24

页数：3

共 15 条

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