ALKYLIDENECARBENES FROM 1,1-DIHALOGENOALKENES WITH SAMARIUM DIIODIDE - MILD AND EFFICIENT METHOD FOR THE SYNTHESIS OF CYCLOPENTENES

被引：45

作者：

KUNISHIMA, M

HIOKI, K

TANI, S

KATO, A

机构：

[1] KOBE GAKUIN UNIV,FAC PHARMACEUT SCI,NISHI KU,KOBE 65121,JAPAN

[2] NIIGATA COLL PHARM,NIIGATA 95021,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 39期

关键词：

D O I：

10.1016/0040-4039(94)85374-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new mild method for construction of cyclopentenes via 1,5-C-H insertion of alkylidenecarbenes by the reaction of 2,2-dialkyl-1,1-dihalogenoalkenes with Sml(2) in benzene-hexamethylphosphoric triamide (HMPA) was developed.

引用

页码：7253 / 7254

页数：2

共 8 条

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