TETRAPHENYLPHOSPHONIUM CIS-TETRABROMOBIS(PYRIDINE)MOLYBDATE(III)

被引：5

作者：

BRENCIC, JV ^{[1
]}

MODEC, B ^{[1
]}

YAO, ZG ^{[1
]}

机构：

[1] TEXAS A&M UNIV,DEPT CHEM,COLLEGE STN,TX 77843

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194007535

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, (C24H20P)[MoBr4(C5H5N)2], contains a cis-[Mo(III)Br4(C5H5N)2]- anion in which Br and N atoms define a slightly distorted octahedron with average Mo-Br and Mo-N(pyridine) distances of 2.580(5) and 2.220(5) angstrom, respectively.

引用

页码：197 / 198

页数：2

共 5 条

[1] CRYSTAL-STRUCTURE OF TRANS-PYH[MOBR4PY2] AND REACTIVITY OF TRANS-PYH[MBR4PY2] (M = MO, W, PY = PYRIDINE) TOWARDS NITROGEN LIGANDS AND BROMINE OXIDATION [J].

BRENCIC, JV ;

CEH, B ;

LEBAN, I ;

MODEC, B ;

ROTAR, R .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (04) :796-800

[2] SYNTHESIS OF CIS-TETRABROMOBISPYRIDINEMOLYBDATES(III) AND THE CRYSTAL-STRUCTURE OF CIS-(NH4)[MOBR4PY2].1/3H2O (PY=PYRIDINE) [J].

BRENCIC, JV ;

LEBAN, I ;

MODEC, B .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (05) :950-954

[3]

ERNRAFNONIUS, 1985, STRUCTURE DETERMINAT

[4]

GABE EJ, 1989, J APPL CRYSTALLOGR, V23, P384

[5] STRUCTURE OF TETRAPHENYLPHOSPHONIUM (BIPYRIDINE)TETRACHLOROMOLYBDATE(III) [PPH4][MOCL4(BPY)] [J].

RICHARDS, RL ;

SHORTMAN, C ;

POVEY, DC ;

SMITH, GW .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 :2091-2093

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