QUASI-ONE-DIMENSIONAL STRUCTURE OF CIS-DICHLOROBIS(2,6-DIMETHYLPHENYL ISOCYANIDE)-PALLADIUM(II), [PD(2,6-(CH3)2C6H3NC)2CL2]

被引：25

作者：

DROUIN, M ^{[1
]}

PERREAULT, D ^{[1
]}

HARVEY, PD ^{[1
]}

MICHEL, A ^{[1
]}

机构：

[1] UNIV SHERBROOKE,DEPT CHIM,SHERBROOKE J1K 2R1,QUEBEC,CANADA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270190011222

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C18H18Cl2N2Pd, M(r) = 439.66, triclinic, P1BAR, a = 8.2168 (9), b = 10.4799 (7), c = 10.8272 (12) angstrom, alpha = 85.966 (7), beta = 80.018 (10), gamma = 86.929 (7)-degrees, V = 915.14 (16) angstrom3, Z = 2, D(x) = 1.596 Mg m-3, mu = 1.29 mm-1, lambda-(Mo K-alpha) = 0.70930 angstrom, F(000) = 439.95, T = 293 K. The structure was refined to R = 0.034, wR = 0.030 for 2100 observed reflections. The Pd atom has a square-planar coordination with the two Cl atoms and the two isocyanide groups in cis configurations. The dihedral angles between the xylenyl isocyanide planes and Pd coordination plane are 20.9 (1) and 46.6 (1)-degrees. The compound forms a quasi linear chain with Pd...Pd separations of 4.186 (2) and 4.061 (2) angstrom, and a Pd...Pd...Pd angle of 170.17 (2)-degrees.

引用

页码：752 / 754

页数：3

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