ON THE MOLECULAR-STRUCTURE OF [FE-3(CO)(12)] IN THE SOLID-STATE

被引：16

作者：

BRAGA, D

FARRUGIA, L

GREPIONI, F

JOHNSON, BFG

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

[2] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,SCOTLAND

[3] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,SCOTLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 464卷 / 02期

关键词：

IRON; CARBONYL;

D O I：

10.1016/0022-328X(94)87283-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The determination of precise, low-temperature crystal structures of [Fe-3(CO)(12)] has shown that, on decreasing the temperature, the bridging ligands become progressively more symmetric, the bridged Fe-Fe bond shortens and the atomic displacement parameters show a congruent behaviour with temperature.

引用

收藏

页码：C39 / C41

页数：3

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